VS 2010 : Show Message Box Error If System.componentmodel.win32exception Occurs?

I created a simple program which basically launches programs installed on 32-bit system in the C:Program Files directory. I purposely put an .exe line of code in the compiler but that .exe wasn't installed on the system, I was expecting for an error when I tried to click the launch button and I did. NOTE: I already have a beginning If statement and that program is actually installed in the system, works perfectly no errors appearing.

ElseIf lstMultimedia.SelectedItem = "HyperCam" Then Process.Start("C:Program FilesHyperCam 2HyCam2.exe") 'this program doesn't exist in the system"

When the error appeared I looked at it in detail and found it was a system.componentmodel.win32exception type of error, I'm guessing that means a file doesn't exist in the directory I specified therefore the program displays an error.Now what I want to do is display a message box saying along the lines "This program cannot be found in your system" or something like that. But I don't know what the actual syntax/code for it, so far from thinking I have this.

Else : lstMultimedia.SelectedItem = 'no idea what to put here Then MessageBox.Show("This application cannot be found in your system or is installed in a different directory", "Error", MessageBoxButtons.OK, MessageBoxIcon.Error)
End If